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Synthesis of a low-bandgap polymer bearing side groups containing phenoxy radicals
http://hdl.handle.net/2241/113828
http://hdl.handle.net/2241/1138285c212199-f9cd-4af7-bb6b-f378ab5df000
名前 / ファイル | ライセンス | アクション |
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JMS_46-20.pdf (292.2 kB)
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Item type | Journal Article(1) | |||||
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公開日 | 2011-09-02 | |||||
タイトル | ||||||
タイトル | Synthesis of a low-bandgap polymer bearing side groups containing phenoxy radicals | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Innami, Yu
× Innami, Yu× Kiebooms, Rafaёl H. L.× Koyano, Tamotsu× Ichinohe, Masaaki× Ohkawa, Satoshi× Kawabata, Kohsuke× Kawamatsu, Masataka× Matsuishi, Kiyoto× Goto, Hiromasa |
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著者別名 |
古谷野, 有
× 古谷野, 有× 一戸, 雅聡× 松石, 清人× 後藤, 博正 |
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抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Poly(isothianaphthene methine) bearing di-tert-butylphenoxide in the side chain was prepared by reacting isothianaphthene and 3,5-di-tert-butyl-4-hydroxybenzaldehyde in the presence of POCl3. A reference polymer with no hydroxy group in the side chain was also synthesized. Both polymers are characterized by a low-bandgap with value of ca. 1.3 eV obtained by optical absorption spectroscopy, and ca. 1.7 eV estimated from an electrochemical method. After treatment with PbO2 as an oxidizer, phenoxy radicals were generated by oxidation in the polymer side groups. Optical absorption measurements and electron spin resonance (ESR) showed a characteristic signal due to phenoxy radicals. Magnetic properties of the polymer were examined with ESR and superconducting quantum interference device (SQUID) measurements. The results suggested that the polymer shows paramagnetic behavior. | |||||
書誌情報 |
Journal of materials science 巻 46, 号 20, p. 6556-6562, 発行日 2011-10 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 0022-2461 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00701725 | |||||
DOI | ||||||
識別子タイプ | DOI | |||||
関連識別子 | 10.1007/s10853-011-5602-9 | |||||
権利 | ||||||
権利情報 | © Springer Science+Business Media, LLC 2011The original publication is available at www.springerlink.com | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Springer Science+Business | |||||
URI | ||||||
識別子 | http://hdl.handle.net/2241/113828 | |||||
識別子タイプ | HDL |