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Journal of organometallic chemistry >
Please use this identifier to cite or link to this item:
http://hdl.handle.net/2241/113008
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| Title: | Versatile bridging ability of secondary thioamide group for constructing metal cluster based on pincer complex |
| Authors: | Okamoto, Ken
Kuwabara, Junpei
Kanbara, Takaki
桑原, 純平
神原, 貴樹 |
| Issue Date: | Mar-2011 |
| Publisher: | Elsevier |
| Journal Title: | Journal of organometallic chemistry |
| Volume: | 696 |
| Issue: | 6 |
| Start Page: | 1305 |
| End Page: | 1309 |
| DOI: | 10.1016/j.jorganchem.2010.11.028 |
| Abstract: | The crystallization of the SCS pincer platinum complex with secondary thioamide groups, [4-methyl-2,6-bis(anilinothiocarbonyl)-κ2S,S’-phenyl-κC1]chloroplatinum(II), spontaneously forms a trinuclear cluster complex accompanied by liberating HCl in DMSO/EtOH mixture. The crystal structure of the SNS pincer copper complex with secondary thioamide groups, [2,5-bis(benzylaminothiocarbonyl)-κ2S,S’-pyrrolyl-κN1]chlorocopper(II), exhibits a dimer structure bearing the bridging thioamide group. The thioamide group acts as the bridging ligand of the multimetallic complexes in different anionic and neutral manners. |
| URI: | http://hdl.handle.net/2241/113008 |
| Rights: | © 2011 Elsevier B.V.
NOTICE: this is the author’s version of a work that was accepted for publication in
Journal of organometallic chemistry. Changes resulting from the publishing process,
such as peer review, editing, corrections, structural formatting, and other quality
control mechanisms may not be reflected in this document. Changes may have been made
to this work since it was submitted for publication. A definitive version was subsequently
published in Journal of organometallic chemistry, Vol.696. Issue:6, Pages:1305-1309.
doi:10.1016/j.jorganchem.2010.11.028 |
| Text Version: | author |
| Appears in Collections: | 桑原 純平 (Kuwabara Junpei)
神原 貴樹 (Kanbara Takaki)
Journal of organometallic chemistry
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