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Please use this identifier to cite or link to this item: http://hdl.handle.net/2241/101644

Title: Femtosecond Dynamics of the Exciton Self-Trapping Process in a Quasi-One-Dimensional Halogen-Bridged Platinum Complex
Authors: Tomimoto, S.
Nansei, H.
Saito, S.
Suemoto, T.
Takeda, J.
Kurita, S.
冨本, 慎一
Issue Date: Jul-1998
Publisher: American Physical Society
Journal Title: Physical review letters
Volume: 81
Issue: 2
Start Page: 417
End Page: 420
DOI: 10.1103/PhysRevLett.81.417
Abstract: Self-trapped-exciton (STE) luminescence of quasi-one-dimensional halogen-bridged platinum complex [Pt(en)2] [Pt(en)2Cl2] (ClO4)4 is investigated by femtosecond time-resolved luminescence spectroscopy. In the high energy tail of the luminescence band, a fast rise and decay are seen, whereas around the luminescence peak energy a slow rise of about 500 fs is observed. This rise becomes faster at the low energy side of the band. These results are consistently explained by the cooling of prethermalized STEs, following the rapid self-trapping which is estimated to occur within 140 fs.
URI: http://hdl.handle.net/2241/101644
Rights: ©1998 The American Physical Society
Text Version: publisher
Appears in Collections:Physical review letters
冨本 慎一 (Tomimoto Sin-iti)

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